Why are concentrations of NOx in the lower troposphere very variable?
— | NO and NO2 are easily interchangeable. |
— | Photolysis quickly splits up NO2. |
— | There are several mechanisms for creating and destroying NOx. |
— | HNO3 acts as a sink for NOx. |
The typical lifespan of NOx in the lower troposphere is short. What are the consequences of this fact for monitoring NOx?
— | Concentrations of NOx in the lower troposphere can be ignored. |
— | NOx concentrations can vary rapidly through time. |
— | Point measurements need to be repeated at short intervals. |
— | Concentrations of NOx tend to even out over time. |
Particular local events such as biomass burning can lead to high local values for NOx emissions. What are the consequences of this fact for monitoring NOx?
— | NOx concentrations can vary considerably from place to place. |
— | The distribution of NOx tends to even out over time. |
— | Point measurements are only valid for their immediate locality. |
— | Point measurements of NOx concentrations need to be averaged over a wider area. |
As a result of the spatial variability of the concentrations of NOx:
— | The area of a point measurement needs to be small. |
— | A large number of point measurements are needed to cover a wide area. |
— | Many values for concentrations of NOx need to be interpolated from a number of point measurements. |
— | The spatial resolution of a point measurement needs to be high. |
What are the limitations on measuring NOx concentrations on a global scale without using satellites?
— | Ground stations cannot measure tropospheric NOx. |
— | Aircraft measurements of NOx are inaccurate. |
— | Many locations are inaccessible. |
— | It is impracticable to make a long series of repeated measurements at short intervals over a large area. |
Measuring the concentrations of trace gases such as NOx in the troposphere from ground stations is difficult. Why?
— | It is difficult to eliminate boundary layer effects. |
— | It is difficult to obtain a reference spectrum for the solar irradiance. |
— | It is difficult to identify weak absorbers in the measured spectra. |
— | It is difficult to establish an altitude profile for a trace gas. |