The task of remote sensing is to measure the concentrations of
specific trace gases in the atmosphere, and particularly in the troposphere.
The presence of a species in the atmosphere can be detected through the
presence of characteristic absorption features in the spectrum of light passing
through the atmosphere, and the concentration of the species from the amount of
absorption that takes place (in accordance with the Beer-Lambert Law).
The process of data retrieval described in this section takes the
earthshine spectrum measured at the satellite for each ground pixel scanned and
derives a value for the concentration of NO2 in the column of
troposphere above that pixel.
This section describes the procedures used to derive the
concentrations of tropospheric NO2 from earthshine spectra.
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Irradiance and earthshine
The nature of the solar irradiance the incident solar radiation
before it encounters the Earth's atmosphere and the use of its
spectrum as a reference against which we can analyse the earthshine spectrum.
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Earthshine interactions
The absorption signature of NO2 in the earthshine spectrum has to be
extracted from the many spectral features that are not the result of NO2
absorption.
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DOAS
The concentrations of NO2 and other trace gases are extracted using
a technique known as Differential Optical Absorption Spectroscopy, or DOAS.
This section presents a graphical and a mathematical treatment of the DOAS
technique.
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SCDtotal to VCDtrop
Our focus of interest is the relatively short 'vertical column' of troposphere
directly above the ground pixel. The DOAS technique yields NO2 concentrations
for the 'total slant column', a long, slanting light path that depends on the
solar zenith angle and the line of sight of the spectrometer towards the ground
pixel. We need to process the total slant column density to arrive at values for the
tropospheric vertical column density of NO2.
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Summary
This section, intended as a revision element, is a step-by-step presentation of
all the major retrieval processes.