REFERENCE SPECTRUM FOR MOLECULAR IODINE I2 AT LOW COLUMN DENSITY ---------------------------------------------------------------- experiment: 18.11.2004 Juan Carlos Gómez-Martín, Peter Spietz second series: ref-181555-1.SPE to ref-181629-20.SPE analysis: Juan Carlos Gómez-Martín, Peter Spietz Published: Spietz, P.; Gómez Martín, J.C.; Burrows, J.P., Effects of column density on I2 spectroscopy and determination of I2 absorption cross section at 500nm, accepted for publication on the Atmospheric Chemistry and Physics Discussions. pressure and column density: - recorded at atmospheric pressure 1000mbar (bath gas N2) - at I2 column density of (1.42 ± 0.038)e16 molec/cm^2 - pathlength = 26.4 cm vertical axis: - optical density, corrected for deposit absorption and drift - scaled to absolute cross section at 500nm using 2.191E-18 cm^/molec (Spietz, Gómez-Martín and Burrows 2005) - uncertainty: maximum of 2.7%*sigma and 7E-20cm^/molec, whichever is larger wavelength axis: - calibrated against convoluted and binned high-resolution FTS spectrum by Marcy and Butler, ± 0.11nm - vacuum wavelength spectroscopic conditions - entrance slit 50 µm -> 0.59 nm FWHM - grating 300 grooves/mm -> 0.154 nm/pixel, blaze 300 nm - pixel size 26 µm x 26 µm, roper scientific CCD version 2005_02_23_ps lambdaVac sigma ---------------------------------- 428.4633 8.4653E-20 428.62581 1.11085E-19 428.78829 8.56933E-20 428.95076 1.13085E-19 429.1132 8.33948E-20 429.27562 9.52864E-20 429.43803 1.15108E-19 429.60041 9.57444E-20 429.76276 1.14687E-19 429.9251 8.96379E-20 430.08742 9.04377E-20 430.24971 1.11565E-19 430.41198 1.16649E-19 430.57423 1.12255E-19 430.73646 1.04118E-19 430.89867 1.26967E-19 431.06086 1.29067E-19 431.22303 1.00711E-19 431.38517 1.01594E-19 431.5473 9.50154E-20 431.7094 1.3841E-19 431.87149 1.2311E-19 432.03355 1.14605E-19 432.19559 1.25073E-19 432.35761 1.3039E-19 432.51961 1.14401E-19 432.68159 1.32667E-19 432.84354 1.30025E-19 433.00548 1.10221E-19 433.16739 1.18544E-19 433.32929 1.13776E-19 433.49116 1.25974E-19 433.65302 1.25346E-19 433.81485 1.12527E-19 433.97666 1.15633E-19 434.13845 1.17063E-19 434.30022 1.47128E-19 434.46197 1.35166E-19 434.6237 1.2256E-19 434.78541 1.17406E-19 434.9471 1.17786E-19 435.10877 1.26501E-19 435.27042 1.35238E-19 435.43205 1.46977E-19 435.59365 1.32493E-19 435.75524 1.41325E-19 435.91681 1.31959E-19 436.07835 1.4126E-19 436.23988 1.31912E-19 436.40138 1.42561E-19 436.56287 1.38733E-19 436.72433 1.67954E-19 436.88578 1.49498E-19 437.0472 1.54046E-19 437.20861 1.6972E-19 437.36999 1.77556E-19 437.53136 1.61663E-19 437.6927 1.60966E-19 437.85402 1.73046E-19 438.01533 1.63485E-19 438.17661 1.527E-19 438.33788 1.78283E-19 438.49912 1.69E-19 438.66035 1.65945E-19 438.82155 1.77916E-19 438.98274 1.79035E-19 439.1439 1.56993E-19 439.30505 1.84674E-19 439.46617 1.83139E-19 439.62728 1.70983E-19 439.78837 2.01303E-19 439.94943 1.7835E-19 440.11048 1.6983E-19 440.27151 1.76134E-19 440.43251 1.73584E-19 440.5935 1.69049E-19 440.75447 2.19662E-19 440.91542 2.0199E-19 441.07635 2.04613E-19 441.23726 1.95378E-19 441.39815 2.2473E-19 441.55902 2.02603E-19 441.71988 1.93481E-19 441.88071 2.33113E-19 442.04152 2.16977E-19 442.20232 1.99965E-19 442.36309 2.05709E-19 442.52385 2.10929E-19 442.68459 2.18138E-19 442.8453 2.07073E-19 443.006 2.19501E-19 443.16668 2.30966E-19 443.32734 2.4571E-19 443.48798 2.13273E-19 443.6486 2.34907E-19 443.80921 2.10484E-19 443.96979 2.31734E-19 444.13036 2.41204E-19 444.2909 2.41532E-19 444.45143 2.56412E-19 444.61194 2.5681E-19 444.77243 2.44276E-19 444.9329 2.71807E-19 445.09335 2.57911E-19 445.25378 2.64272E-19 445.4142 2.68548E-19 445.5746 2.53015E-19 445.73497 2.55313E-19 445.89533 2.57929E-19 446.05567 2.77138E-19 446.21599 2.74151E-19 446.37629 2.61289E-19 446.53658 2.57976E-19 446.69684 3.01617E-19 446.85709 2.63645E-19 447.01732 2.79905E-19 447.17753 2.83771E-19 447.33772 2.90348E-19 447.4979 2.97757E-19 447.65805 2.87656E-19 447.81819 3.15675E-19 447.97831 3.09446E-19 448.13841 2.94947E-19 448.29849 3.05781E-19 448.45855 2.93681E-19 448.6186 3.07558E-19 448.77863 3.14089E-19 448.93864 2.98618E-19 449.09863 3.65467E-19 449.2586 4.03201E-19 449.41856 4.31677E-19 449.57849 3.57165E-19 449.73841 3.1192E-19 449.89831 3.07482E-19 450.0582 3.0829E-19 450.21806 3.05551E-19 450.37791 3.30854E-19 450.53774 3.35994E-19 450.69755 3.66603E-19 450.85734 3.43009E-19 451.01712 3.33164E-19 451.17688 3.50171E-19 451.33662 3.77404E-19 451.49634 3.72679E-19 451.65605 4.20804E-19 451.81573 4.25395E-19 451.9754 3.75072E-19 452.13506 3.73096E-19 452.29469 3.75101E-19 452.45431 3.65634E-19 452.61391 3.68073E-19 452.77349 4.05347E-19 452.93306 4.03198E-19 453.0926 3.91801E-19 453.25213 3.91011E-19 453.41165 4.23091E-19 453.57114 4.26968E-19 453.73062 4.01426E-19 453.89008 4.14275E-19 454.04952 4.47992E-19 454.20895 4.32479E-19 454.36836 4.50467E-19 454.52775 4.51476E-19 454.68712 4.39418E-19 454.84648 4.47681E-19 455.00582 4.58191E-19 455.16514 4.46287E-19 455.32445 4.38026E-19 455.48374 4.64056E-19 455.64301 4.66396E-19 455.80227 4.86234E-19 455.96151 4.87052E-19 456.12073 4.79813E-19 456.27993 4.91478E-19 456.43912 4.902E-19 456.59829 4.93332E-19 456.75744 5.02883E-19 456.91658 4.97387E-19 457.0757 5.00553E-19 457.23481 5.11625E-19 457.39389 5.19922E-19 457.55296 5.02823E-19 457.71202 5.23832E-19 457.87105 5.43969E-19 458.03008 5.27939E-19 458.18908 5.20506E-19 458.34807 5.33876E-19 458.50704 5.40555E-19 458.66599 5.51583E-19 458.82493 5.48715E-19 458.98385 5.56943E-19 459.14276 5.55483E-19 459.30165 5.74985E-19 459.46052 5.57789E-19 459.61937 5.63031E-19 459.77821 5.69042E-19 459.93704 5.74292E-19 460.09585 5.70352E-19 460.25464 6.02429E-19 460.41341 6.08993E-19 460.57217 6.06461E-19 460.73091 5.9434E-19 460.88964 5.95457E-19 461.04835 6.12657E-19 461.20705 6.19827E-19 461.36572 6.33869E-19 461.52439 6.56757E-19 461.68303 6.32853E-19 461.84166 6.56434E-19 462.00028 6.67315E-19 462.15888 6.85176E-19 462.31746 6.61857E-19 462.47603 6.51749E-19 462.63458 6.60073E-19 462.79311 6.61155E-19 462.95163 6.80488E-19 463.11014 6.79091E-19 463.26863 6.68787E-19 463.4271 6.61084E-19 463.58556 6.78441E-19 463.744 6.79521E-19 463.90242 6.71637E-19 464.06083 7.01072E-19 464.21923 7.23838E-19 464.37761 7.09747E-19 464.53597 7.12923E-19 464.69432 6.99609E-19 464.85265 7.33193E-19 465.01097 7.25856E-19 465.16927 7.25665E-19 465.32756 7.25876E-19 465.48583 7.30578E-19 465.64409 7.25836E-19 465.80233 7.483E-19 465.96056 7.59346E-19 466.11877 7.67119E-19 466.27696 7.89369E-19 466.43514 7.94225E-19 466.59331 7.97518E-19 466.75146 8.14969E-19 466.90959 8.54482E-19 467.06771 8.44031E-19 467.22582 8.41112E-19 467.38391 8.22943E-19 467.54198 8.21493E-19 467.70004 7.97914E-19 467.85809 8.22669E-19 468.01612 8.4229E-19 468.17414 8.1905E-19 468.33214 8.25814E-19 468.49012 8.36186E-19 468.64809 8.46851E-19 468.80605 8.69157E-19 468.96399 8.64424E-19 469.12192 8.4883E-19 469.27983 8.76405E-19 469.43773 8.60438E-19 469.59561 9.00465E-19 469.75348 8.85764E-19 469.91133 9.06446E-19 470.06917 9.07629E-19 470.227 8.8566E-19 470.38481 8.94457E-19 470.5426 9.18572E-19 470.70039 9.14822E-19 470.85815 9.12799E-19 471.01591 9.28757E-19 471.17365 9.41665E-19 471.33137 9.36621E-19 471.48908 9.30874E-19 471.64678 9.52522E-19 471.80446 9.60764E-19 471.96212 9.38412E-19 472.11978 9.66176E-19 472.27742 9.87698E-19 472.43504 9.60421E-19 472.59265 9.89939E-19 472.75025 9.91264E-19 472.90783 1.03071E-18 473.0654 1.06901E-18 473.22296 1.08679E-18 473.3805 1.03499E-18 473.53802 9.88344E-19 473.69554 9.77521E-19 473.85303 9.93313E-19 474.01052 1.03687E-18 474.16799 1.02953E-18 474.32545 1.04471E-18 474.48289 1.07461E-18 474.64032 1.05167E-18 474.79774 1.06556E-18 474.95514 1.06523E-18 475.11253 1.07929E-18 475.26991 1.05698E-18 475.42727 1.08709E-18 475.58462 1.07059E-18 475.74195 1.12933E-18 475.89927 1.11462E-18 476.05658 1.10271E-18 476.21388 1.11871E-18 476.37116 1.14137E-18 476.52842 1.12202E-18 476.68568 1.14103E-18 476.84292 1.14441E-18 477.00015 1.15797E-18 477.15736 1.16044E-18 477.31456 1.16755E-18 477.47175 1.17496E-18 477.62892 1.19183E-18 477.78608 1.19074E-18 477.94323 1.195E-18 478.10037 1.20626E-18 478.25749 1.21733E-18 478.4146 1.21552E-18 478.57169 1.22396E-18 478.72878 1.24043E-18 478.88585 1.25922E-18 479.0429 1.23041E-18 479.19995 1.2636E-18 479.35698 1.26551E-18 479.51399 1.27353E-18 479.671 1.27191E-18 479.82799 1.28164E-18 479.98497 1.28468E-18 480.14194 1.30536E-18 480.29889 1.31187E-18 480.45583 1.34322E-18 480.61276 1.36114E-18 480.76968 1.35675E-18 480.92658 1.35008E-18 481.08347 1.34476E-18 481.24035 1.33445E-18 481.39721 1.337E-18 481.55407 1.33655E-18 481.71091 1.33659E-18 481.86773 1.35188E-18 482.02455 1.36261E-18 482.18135 1.37914E-18 482.33814 1.39322E-18 482.49492 1.39645E-18 482.65169 1.41313E-18 482.80844 1.40747E-18 482.96518 1.42588E-18 483.12191 1.42562E-18 483.27863 1.42471E-18 483.43533 1.45061E-18 483.59202 1.43487E-18 483.7487 1.4615E-18 483.90537 1.45668E-18 484.06203 1.46819E-18 484.21867 1.47577E-18 484.3753 1.47767E-18 484.53192 1.50055E-18 484.68853 1.49911E-18 484.84512 1.48357E-18 485.00171 1.5161E-18 485.15828 1.50267E-18 485.31484 1.54832E-18 485.47139 1.54233E-18 485.62792 1.53768E-18 485.78445 1.53846E-18 485.94096 1.53526E-18 486.09746 1.56449E-18 486.25395 1.57027E-18 486.41043 1.57272E-18 486.56689 1.58401E-18 486.72335 1.58516E-18 486.87979 1.58593E-18 487.03622 1.60173E-18 487.19264 1.61229E-18 487.34905 1.61376E-18 487.50545 1.6113E-18 487.66183 1.63143E-18 487.8182 1.64895E-18 487.97457 1.6331E-18 488.13092 1.64993E-18 488.28726 1.6632E-18 488.44358 1.66576E-18 488.5999 1.66443E-18 488.75621 1.67666E-18 488.9125 1.69674E-18 489.06878 1.68244E-18 489.22505 1.7132E-18 489.38131 1.70756E-18 489.53756 1.70528E-18 489.6938 1.72772E-18 489.85003 1.73622E-18 490.00624 1.73698E-18 490.16245 1.744E-18 490.31864 1.74865E-18 490.47483 1.7535E-18 490.631 1.76852E-18 490.78716 1.78807E-18 490.94331 1.7812E-18 491.09945 1.78779E-18 491.25558 1.79765E-18 491.41169 1.82118E-18 491.5678 1.84393E-18 491.7239 1.84017E-18 491.87998 1.85442E-18 492.03606 1.84039E-18 492.19212 1.80857E-18 492.34817 1.83984E-18 492.50422 1.84271E-18 492.66025 1.85701E-18 492.81627 1.8723E-18 492.97228 1.87022E-18 493.12828 1.88018E-18 493.28427 1.87306E-18 493.44025 1.88887E-18 493.59622 1.89332E-18 493.75218 1.88236E-18 493.90812 1.91321E-18 494.06406 1.91864E-18 494.21999 1.92355E-18 494.37591 1.92366E-18 494.53181 1.94019E-18 494.68771 1.94639E-18 494.8436 1.95574E-18 494.99947 1.96937E-18 495.15534 1.95907E-18 495.31119 1.98704E-18 495.46704 1.97635E-18 495.62287 1.98494E-18 495.7787 1.99046E-18 495.93451 1.99597E-18 496.09032 2.00515E-18 496.24611 1.99882E-18 496.4019 2.01891E-18 496.55768 2.0272E-18 496.71344 2.04701E-18 496.8692 2.05477E-18 497.02494 2.04054E-18 497.18068 2.0531E-18 497.3364 2.06194E-18 497.49212 2.08499E-18 497.64783 2.09068E-18 497.80352 2.09582E-18 497.95921 2.08995E-18 498.11489 2.10084E-18 498.27056 2.09902E-18 498.42622 2.10588E-18 498.58186 2.12592E-18 498.7375 2.11949E-18 498.89313 2.14144E-18 499.04875 2.13147E-18 499.20436 2.15733E-18 499.35997 2.15663E-18 499.51556 2.15996E-18 499.67114 2.17466E-18 499.82671 2.17995E-18 499.98228 2.17664E-18 500.13783 2.1843E-18 500.29338 2.17465E-18 500.44891 2.195E-18 500.60444 2.19906E-18 500.75996 2.2076E-18 500.91547 2.20881E-18 501.07096 2.21467E-18 501.22645 2.22962E-18 501.38194 2.23361E-18 501.53741 2.22569E-18 501.69287 2.2342E-18 501.84832 2.26029E-18 502.00377 2.26561E-18 502.15921 2.27571E-18 502.31463 2.27905E-18 502.47005 2.28284E-18 502.62546 2.30037E-18 502.78086 2.28213E-18 502.93625 2.29556E-18 503.09163 2.30384E-18 503.24701 2.30781E-18 503.40237 2.30909E-18 503.55773 2.33858E-18 503.71308 2.29891E-18 503.86842 2.31416E-18 504.02375 2.34635E-18 504.17907 2.3456E-18 504.33438 2.29928E-18 504.48969 2.35431E-18 504.64499 2.39076E-18 504.80027 2.34657E-18 504.95555 2.34659E-18 505.11082 2.39878E-18 505.26609 2.40859E-18 505.42134 2.38255E-18 505.57659 2.34544E-18 505.73182 2.43538E-18 505.88705 2.44713E-18 506.04227 2.40835E-18 506.19749 2.36806E-18 506.35269 2.41597E-18 506.50789 2.46401E-18 506.66308 2.46309E-18 506.81826 2.42277E-18 506.97343 2.39286E-18 507.12859 2.46362E-18 507.28375 2.51611E-18 507.43889 2.47113E-18 507.59403 2.41044E-18 507.74917 2.42098E-18 507.90429 2.49566E-18 508.05941 2.55792E-18 508.21451 2.50855E-18 508.36961 2.42758E-18 508.52471 2.44341E-18 508.67979 2.49702E-18 508.83487 2.57543E-18 508.98994 2.54028E-18 509.145 2.4898E-18 509.30005 2.41913E-18 509.4551 2.47278E-18 509.61013 2.58035E-18 509.76516 2.61185E-18 509.92019 2.55946E-18 510.0752 2.49048E-18 510.23021 2.42782E-18 510.38521 2.49563E-18 510.5402 2.63946E-18 510.69519 2.65036E-18 510.85017 2.58185E-18 511.00514 2.50595E-18 511.1601 2.45433E-18 511.31506 2.49712E-18 511.47 2.6719E-18 511.62495 2.70633E-18 511.77988 2.62591E-18 511.93481 2.57041E-18 512.08973 2.49069E-18 512.24464 2.45569E-18 512.39954 2.57889E-18 512.55444 2.73426E-18 512.70933 2.72063E-18 512.86422 2.65268E-18 513.01909 2.56606E-18 513.17396 2.47829E-18 513.32882 2.47992E-18 513.48368 2.63508E-18 513.63853 2.81127E-18 513.79337 2.76514E-18 513.94821 2.68065E-18 514.10303 2.56734E-18 514.25785 2.49689E-18 514.41267 2.48234E-18 514.56748 2.61645E-18 514.72228 2.82269E-18 514.87707 2.8146E-18 515.03186 2.70841E-18 515.18664 2.63667E-18 515.34141 2.5813E-18 515.49618 2.49369E-18 515.65094 2.5022E-18 515.8057 2.71222E-18 515.96044 2.87448E-18 516.11519 2.83553E-18 516.26992 2.74687E-18 516.42465 2.64517E-18 516.57937 2.54418E-18 516.73409 2.46373E-18 516.8888 2.49513E-18 517.0435 2.76602E-18 517.1982 2.95144E-18 517.35289 2.87876E-18 517.50757 2.79063E-18 517.66225 2.67442E-18 517.81692 2.56158E-18 517.97158 2.48705E-18 518.12624 2.46499E-18 518.2809 2.66402E-18 518.43554 2.93341E-18 518.59018 2.94238E-18 518.74482 2.87176E-18 518.89945 2.73662E-18 519.05407 2.6222E-18 519.20869 2.56834E-18 519.3633 2.49167E-18 519.5179 2.48918E-18 519.6725 2.73856E-18 519.8271 2.98784E-18 519.98168 2.96643E-18 520.13626 2.86996E-18 520.29084 2.765E-18 520.44541 2.65634E-18 520.59997 2.55389E-18 520.75453 2.45536E-18 520.90909 2.43899E-18 521.06363 2.66983E-18 521.21818 3.03085E-18 521.37271 3.04418E-18 521.52724 2.93264E-18 521.68177 2.83209E-18 521.83629 2.7166E-18 521.9908 2.60472E-18 522.14531 2.49349E-18 522.29981 2.41136E-18 522.45431 2.45334E-18 522.6088 2.84383E-18 522.76329 3.1204E-18 522.91777 3.06832E-18 523.07225 2.94388E-18 523.22672 2.81005E-18 523.38119 2.67051E-18 523.53565 2.57245E-18 523.6901 2.44024E-18 523.84455 2.37318E-18 523.999 2.42942E-18 524.15344 2.86305E-18 524.30787 3.15816E-18 524.4623 3.08881E-18 524.61673 2.98407E-18 524.77115 2.84192E-18 524.92556 2.70402E-18 525.07997 2.58978E-18 525.23438 2.49167E-18 525.38878 2.37386E-18 525.54318 2.35758E-18 525.69757 2.62515E-18 525.85195 3.08931E-18 526.00633 3.16083E-18 526.16071 3.07028E-18 526.31508 2.93662E-18 526.46945 2.80599E-18 526.62381 2.6689E-18 526.77817 2.53657E-18 526.93252 2.44261E-18 527.08687 2.33189E-18 527.24122 2.32644E-18 527.39555 2.65463E-18 527.54989 3.13646E-18 527.70422 3.20379E-18 527.85855 3.07645E-18 528.01287 2.95007E-18 528.16719 2.80408E-18 528.3215 2.66524E-18 528.47581 2.5408E-18 528.63011 2.45004E-18 528.78441 2.3658E-18 528.93871 2.27686E-18 529.093 2.46745E-18 529.24729 3.00548E-18 529.40157 3.22397E-18 529.55585 3.14798E-18 529.71012 2.99771E-18 529.86439 2.84004E-18 530.01866 2.73338E-18 530.17292 2.58871E-18 530.32718 2.49332E-18 530.48144 2.36916E-18 530.63569 2.26565E-18 530.78993 2.21979E-18 530.94418 2.49441E-18 531.09842 3.04277E-18 531.25265 3.22409E-18 531.40688 3.13277E-18 531.56111 3.00861E-18 531.71533 2.86269E-18 531.86955 2.7277E-18 532.02377 2.58305E-18 532.17798 2.42821E-18 532.33219 2.31848E-18 532.4864 2.20083E-18 532.6406 2.14894E-18 532.7948 2.30187E-18 532.94899 2.90405E-18 533.10318 3.24167E-18 533.25737 3.19008E-18 533.41155 3.03127E-18 533.56573 2.90678E-18 533.71991 2.73961E-18 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