On the Evolution of Arctic Lower Stratospheric Ozone in Spring 97, Ground-Based Microwave Measurements at Ny-Ålesund, Spitsbergen

J. Langer, B.-M. Sinnhuber, U. Klein, K. F. Künzi
Institute of Environmental Physics, University of Bremen, PO Box 33 04 40, D-28334 Bremen, Germany

INSTRUMENT

As primary station of the Network for the Detection of Stratospheric Change (NDSC), Ny-Ålesund (78,9°N 11,9°E) plays an important role in the ground-based monitoring of the Arctic stratosphere. A microwave radiometer belonging to the standard instrumentation of each station is operated at Ny-Ålesund by the Institute of Environmental Physics (University of Bremen) on behalf of the Alfred-Wegener-Institute for Polar and Marine Research. The principle of microwave radiometry is based on the detection of a pressure broadened emission line of trace gases in the microwave frequency range. From the shape of the detected line volume mixing ratio (VMR) profiles are retrieved.

Table 1. Instrument parameters Table 2. Retrieval parameters
frequency 14.175 GHz time coverage all year round, nearly weather indipendent
system noise temperature 3200 K time resolution 1-5 profiles per hour>
bandwidth 1.65 GHz vertical resolution 10-15 km, altitude dependent
frequency resolution 1.17 MHz altitude range 12-55 km
precision 0.1 ppm at 20 km

RESULTS WINTER 96/97

In early 1997 microwave measurements at Ny-Ålesund show a substantial ozone decrease at lower stratospheric levels. For a layer centered at the 475 K isentropic level an ozone decrease of about 30 % is observed from mid February to mid April. Taking into account that microwave retrievals lead to averaged results over a 10 km altitude range, depletion in thin layers is expected to be even higher. With regard to the vertical resolution of our measurements, we found ozone depletion over an altitude range extending at least some kms between 475 K to 675 K (20 to 25 km). Calculations of potential vorticity on the 475 K isentropic level revealed that in early 97 Ny-Ålesund was located well inside the polar vortex, except for two periods in mid February and mid April (day 107) when the vortex edge moved across Ny-Ålesund. Especially for the outer-vortex situation around day 107 higher ozone values were measured. After the breakdown of the vortex at the end of April ozone values returned back to normal.

Figure 1. Potential vorticity (thick) and Temperature at the 475 K isentropic level for Ny-Ålesund. The approximate PSC formation temperature is indicated by the dashed line.

Figure 2. Microwave measurements of ozone in the lower stratosphere at Ny-Ålesund for mid February to mid May 1997. In the left part the ozone VMR between 12 and 35 km is shown. Contour lines indicate levels of constant VMR [ppm]. Heights corresponding to isentropic levels 400 K, 475 K and 675 K are indicated by thick lines.Isentropic levels were calculated using daily NMC pressure and temperature profiles. In the right part the measured ozone evolution on layers centered at 400 K, 475 K and 675 K isentropic levels is displayed. A linear regression was performed to estimate the mean ozone decrease on the three isentropic levels during spring 1997. The regression covers the period between day 53 and day 96 while Ny-Ålesund was located well inside the polar vortex as indicated by high and nearly constant PV on the 475 K isentropic level (Figure 1). Solid lines represent linear regressions. Errors (not indicated) are summarized in Table 3. We conclude that the strong ozone decrease is due to chemical ozone depletion. This is confirmed by low stratospheric temperatures necessary for PSC formation and the observation of enhanced ClO at Ny-Ålesund by the RAM [1]. Vortex dynamics including diabatic vertical movement is excluded as major cause for the ozone decrease. Only minor corrections to the amount of chemical ozone loss are expected if the diabatic descent in taken into account since radiative cooling decreases with increasing sunlit hours in spring. Also mixing at the vortex-edge is unimportant in spring 1997 due to the strong and stable vortex centered at the north pole.

Table 3. Mean ozone decrease

daily decrease total decrease
400 K isentropic level 10 ± 1 ppb 0.45 ± 0.04 ppb
475 K isentropic level 24 ± 1 ppb 1.05 ± 0.04 ppb
675 K isentropic level 20 ± 2 ppb 0.91 ± 0.08 ppb
column above 12.5 km 1 ± 1 DU 44 ± 4 DU

Figure 3. Ozone columns above 12.5 km at Ny-Ålesund as calculated from microwave VMR-profiles. The VMR-profiles are transformed to number densities using NMC pressure and temperature profiles. Number density profiles are integrated above 12.5 km taking into account the characteristics of the VMR retrieval. The precision is about 5%. The thin line indicates mean ozone decrease.

ACKNOWLEDGMENTS

This work was supported by the Alfred Wegener Institute for Polar and Marine Research, the European Community (European Stratospheric Monitoring Stations in the Arctic II) and the German Federal Ministry of Education and Research (Ozonforschungsprogramm)

REFERENCES

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